Pd(acac)2/Xantphos: A highly efficient and readily available catalyst for regioselective hydrosilylation of allenes. (13th November 2020)

• Record Type: Journal Article
• Authors: Liu, Xiao-Tao; Zhang, Guo-Liang; Zeng, Jia-Hao; Hu, Jing; Zhan, Zhuang-Ping
• Is Part Of: Phosphorus, sulfur, and silicon and the related elements. Volume 196:Number 4(2021)
• Page Start: 349
• Page End: 352
• Publication Date: 2020-11-13
• Subjects: Hydrosilylation -- branched allylsilanes; Sulfur compounds -- Periodicals; Organosulfur compounds -- Periodicals; Phosphorus compounds -- Periodicals; Organophosphorus compounds -- Periodicals; Silicon compounds -- Periodicals; Organosilicon compounds -- Periodicals; 546
• DOI: 10.1080/10426507.2020.1845683
• Languages: English
• ISSNs: 1042-6507

Abstract

Abstract: A convenient and efficient Pd(acac)2 /Xantphos-catalyzed regioselective hydrosilylation of allenes has been developed. This convenient catalyst proved to be suitable for a broad range of allenes, offering a general and efficient route to branched allylsilanes in high yields with exceptional regioselectivity. A Pd(0) species involved mechanism is proposed. Graphical Abstract: