Advanced microstructural characterization of transgranular Pb-caustic SCC in Alloy 690TT. (15th August 2022)

• Record Type: Journal Article
• Authors: Mazzei, G.B.; Burke, M.G.; Horner, D.A.; Scenini, F.
• Is Part Of: Corrosion science. Volume 205(2022)
• Publication Date: 2022-08-15
• Subjects: Ni-base alloys (A) -- TEM (B) -- STEM-EDX microanalysis (B) -- Stress corrosion (C) -- De-alloying (C) -- Alkaline corrosion (C); Corrosion and anti-corrosives -- Periodicals; 620.11223
• DOI: 10.1016/j.corsci.2022.110461
• Languages: English
• ISSNs: 0010-938X

Abstract

Abstract: Alloy 690TT was tested at 340 °C in mildly caustic environments containing lead (Pb) to investigate the transgranular cracking mechanism of Pb-induced stress corrosion cracking (PbSCC). Advanced electron microscopy characterization revealed that the fracture surfaces exhibited evidence of cleavage and regions with significant enrichment of metallic Ni, which maintained the same orientation as the original grain matrix. Moreover, there are some indications that crystallographic cracking along {100} and {110} planes is possible at high pH in Pb-containing environment. These experimental observations are consistent with a form of film-induced cleavage mechanism, assisted by de-alloying and exacerbated by planar slip in the matrix. Highlights: The mechanism of caustic-PbSCC on Alloy 690 was studied using advanced electron microscopy. Crystallographic cracking occurred along {100} and {110} planes. Caustic-PbSCC is associated with form of film-rupture/slip-dissolution mechanism. Crack propagation is assisted by extensive planar slip in the matrix and de-alloying.