Newer developments in the green synthesis of tertiary phosphine oxides, phosphinates, phosphonates and their derivatives. (22nd June 2022)

• Record Type: Journal Article
• Authors: Keglevich, György; Harsági, Nikoletta; Varga, Petra R.; Huszár, Bianka; Henyecz, Réka; Kiss, Nóra Z.; Mucsi, Zoltán; Bagi, Péter
• Is Part Of: Phosphorus, sulfur, and silicon and the related elements. Volume 197:Number 5/6(2022)
• Page Start: 420
• Page End: 425
• Publication Date: 2022-06-22
• Subjects: Phosphonic derivatives -- esterification/hydrolysis -- Hirao reaction -- Kabachnik–Fields reaction -- phosphorylation -- rearrangement -- microwave; Sulfur compounds -- Periodicals; Organosulfur compounds -- Periodicals; Phosphorus compounds -- Periodicals; Organophosphorus compounds -- Periodicals; Silicon compounds -- Periodicals; Organosilicon compounds -- Periodicals; 546
• DOI: 10.1080/10426507.2021.1990924
• Languages: English
• ISSNs: 1042-6507

Abstract

Abstract: In this conference proceeding, our newest results on the two-step esterification of phenylphosphonic acid (1/A1 and A2 ), on the hydrolysis of arylphosphonates (1/B ) and other related compounds, on the Ni-catalyzed Hirao P–C coupling reaction (2/A ), on the Kabachnik–Fields reaction of carboxylic amides (2/B ), and on the reactions of α-hydroxyphosphonates, such as their phosphorylation (3/A ) and rearrangement reactions (3/B ) were summarized. Graphical Abstract: UF0001