Sr‐Doped Superionic Hydrogen Glass: Synthesis and Properties of SrH22. Issue 27 (3rd June 2022) - Semenok, Dmitrii V.
Abstract: Recently, several research groups announced reaching the point of metallization of hydrogen above 400 GPa. Despite notable progress, detecting superconductivity in compressed hydrogen remains an unsolved problem. Following the mainstream of extensive investigations of compressed metal polyhydrides, here small doping of molecular hydrogen by strontium is demonstrated to lead to a dramatic reduction in the metallization pressure to ≈200 GPa. Studying the high‐pressure chemistry of the Sr–H system, the formation of several new phases is observed: C 2/ m‐ Sr3 H13, pseudocubic SrH6, SrH9 with cubic F 4 ¯ 3 m $F\bar{4}3m$ ‐Sr sublattice, and pseudo tetragonal superionic P 1‐SrH22, the metal hydride with the highest hydrogen content (96 at%) discovered so far. High diffusion coefficients of hydrogen in the latter phase D H = 0.2–2.1 × 10 −9 m 2 s −1 indicate an amorphous state of the H‐sublattice, whereas the strontium sublattice remains solid. Unlike Ca and Y, strontium forms molecular semiconducting polyhydrides, whereas calcium and yttrium polyhydrides are high‐ T C superconductors with an atomic H sublattice. The discovered SrH22, a kind of hydrogen sponge, opens a new class of materials with ultrahigh content of hydrogen. Abstract : Under high pressure, strontium reacts with hydrogen forming molecular SrH22 —a yellow‐orange semiconductor with the bandgap of ≈1.8 eV. SrH22 has a glassy superionic hydrogen sublattice stabilized by a solid framework of Sr atoms. The formation of hydrogen glass is a new phenomenon that may have a significant impact on the development of new materials for hydrogen storage and high‐pressure electrochemistry.