Living supramolecular polymerization of an amphiphilic aza-BODIPY dye realized by water-assisted kinetic trapping. Issue 55 (21st June 2022)

• Record Type: Journal Article
• Authors: Liu, Yan; Pan, Hongfei; Yuan, Siyuan; Ding, Jiahui; Jiang, Yuanyuan; Ren, Xiang-Kui; Chen, Zhijian
• Is Part Of: Chemical communications. Volume 58:Issue 55(2022)
• Page Start: 7662
• Page End: 7665
• Publication Date: 2022-06-21
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d2cc02437c
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A kinetic-controlled aggregation pathway of amphiphilic aza-BODIPY 1 was established by using H2 O as a co-solvent in MeOH and living supramolecular polymerization was realized for this dye. Abstract : The kinetic assembly pathways of a newly synthesized amphiphilic aza-BODIPY dye 1 were tuned by using H2 O as a co-solvent in MeOH. Accordingly, the biphasic aggregation pathways resulting in kinetically-trapped and thermodynamically stable aggregates of 1 were established and the multiple cyclic seeded living supramolecular polymerization of this dye was realized.