[Na4(N5)4(H2O)2]·H2O·2MeOH: a honeycomb-like sodium pentazolate framework with helical chains. Issue 27 (30th June 2022)

• Record Type: Journal Article
• Authors: Xu, Yuangang; Xu, Ze; Zhang, Xiaopeng; Hou, Tianyang; Lu, Ming
• Is Part Of: CrystEngComm. Volume 24:Issue 27(2022)
• Page Start: 4853
• Page End: 4856
• Publication Date: 2022-06-30
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/d2ce00713d
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : A new NaN5 framework, [Na4 (N5 )4 (H2 O)2 ]·H2 O·2MeOH, was synthesized. It features a UNJ-type zeolite topology with double right-handed helical chains constructing enclosed homochiral channels filled with water and methanol molecules. Abstract : A new NaN5 framework, [Na4 (N5 )4 (H2 O)2 ]·H2 O·2MeOH, was synthesized by changing the content of auxiliary ligands. It features a UNJ-type zeolite topology with double right-handed helical chains constructing enclosed channels filled with water and methanol molecules. This work demonstrates the structural diversity of NaN5 frameworks, and their self-assembly can be regulated using appropriate solvents and additives.