Reversible binding of dinitrogen on a thiolate-bridged cobalt–ruthenium complex supported by a flexible bidentate phosphine ligand. Issue 26 (20th June 2022)

• Record Type: Journal Article
• Authors: Dong, Wenjing; Yang, Dawei; Mei, Tao; Wang, Baomin; Qu, Jingping
• Is Part Of: Dalton transactions. Volume 51:Issue 26(2022)
• Page Start: 9978
• Page End: 9982
• Publication Date: 2022-06-20
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d2dt01534j
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Reversible N2 coordination was achieved on a thiolate-bridged cobalt–ruthenium scaffold supported by a flexible bidentate phosphine ligand. Abstract : A well-defined thiolate-bridged cobalt–ruthenium complex is demonstrated to reversibly bind N2 by modulation of the auxiliary phosphine ligand, which is evidenced by time-dependent 1 H NMR spectroscopy at different temperatures. Notably, this heterobimetallic system represents the first example that can realize N2 coordination on a sulfur-rich Co–Ru cooperative scaffold.