Transient optical absorption as a powerful tool for engineering of lead tungstate scintillators towards faster response. Issue 25 (17th June 2022)

• Record Type: Journal Article
• Authors: Tamulaitis, Gintautas; Nargelas, Saulius; Korjik, Mikhail; Mechinsky, Vitaliy; Talochka, Yauheni; Vaitkevičius, Augustas; Vasil'ev, Andrey
• Is Part Of: Journal of materials chemistry. Volume 10:Issue 25(2022)
• Page Start: 9521
• Page End: 9529
• Publication Date: 2022-06-17
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d2tc01450e
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : Transient optical techniques are exploited to study the origin of accelerated luminescence decay in heavily doped lead tungstate scintillators. Abstract : Transient optical absorption in the pump and probe configuration and the light-induced transient gratings technique is demonstrated to be a useful tool to support time-resolved photoluminescence spectroscopy in studying the processes responsible for timing properties of self-activated scintillating materials. Lead tungstate (PbWO4, PWO) doped by lanthanum and yttrium up to high concentrations of 1500 ppm was studied as a prospective scintillator for fast timing applications in high energy physics. Strong localization of nonequilibrium carriers at radiative recombination centers of one type is evidenced, and the observed acceleration of the luminescence decay in heavily doped PWO is interpreted in view of the inequivalent surrounding of the oxyanionic complexes WO4 2− acting as radiative recombination centers together with dipole–dipole interaction between excited complexes at high levels of excitation.