Host and guest joining forces: a holistic approach for metal–organic frameworks in nonlinear optics. Issue 25 (20th June 2022)

• Record Type: Journal Article
• Authors: Wolf, Mathias; Hirai, Kenji; Toyouchi, Shuichi; Daelemans, Brent; Fron, Eduard; Uji-i, Hiroshi
• Is Part Of: Journal of materials chemistry. Volume 10:Issue 25(2022)
• Page Start: 9471
• Page End: 9477
• Publication Date: 2022-06-20
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d2tc01075e
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : Metal–organic frameworks (MOFs) are interesting candidates for nonlinear optics (NLO). Here, it will be demonstrated how combining host and guest emission can greatly improve NLO performance of MOFs by accommodating Li@C60 into MOF-177. Abstract : Metal–organic frameworks (MOFs) are interesting candidates for applications in nonlinear optics (NLO). However, current design strategies for MOFs in NLO are typically limited to either engineering the MOF itself or using the MOF to align NLO-active molecules within its pores. But more design factors can be considered when engineering MOFs and choosing guest molecules. The NLO emission of the host and guests can be combined instead of using only either one of the two. The interaction between the host and guest can be a source for further improvement by changing the symmetry, dipole moment, bond lengths, charge distribution, etc. Additionally, unstable NLO molecules can potentially be stabilized by accommodation in the MOF. Here, we demonstrate a new strategy for MOFs by combining MOF-177 as a host and Li@C60 as a guest for NLO, meaning that both the MOF itself as well as the guest molecules are emitting NLO signals, as well as further increasing the emission using their interaction elongating bonds within the MOF, thus fully using the MOF's potential for second harmonic generation. Using this approach, the overall emission can be boosted by 40% compared to MOF-177 alone. Furthermore, the accommodation into MOF-177 stabilizes Li@C60 that is normally unstable under ambient conditions without a counterion.