Field-effect conductivity scaling for two-dimensional materials with tunable impurity density. (1st July 2022)

• Record Type: Journal Article
• Authors: Wang, Chulin; Peng, Lintao; Wells, Spencer A; Cain, Jeffrey D; Huang, Yi-Kai; Rhoads, Lawrence A; Dravid, Vinayak P; Hersam, Mark C; Grayson, Matthew A
• Is Part Of: 2D materials. Volume 9:Number 3(2022)
• Publication Date: 2022-07-01
• Subjects: 2D electronics -- ionized impurities -- negative bias instability -- electronic transport -- black phosphorous -- bismuth selenide -- deep-level transient spectroscopy; Graphene -- Periodicals; Materials science -- Periodicals; Nanostructured materials -- Periodicals; 620.115
• DOI: 10.1088/2053-1583/ac72b0
• Languages: English
• ISSNs: 2053-1583

Abstract

Abstract: A scaling law is demonstrated in the conductivity of gated two-dimensional (2D) materials with tunable concentrations of ionized impurity scatterers. Experimental data is shown to collapse onto a single 2D conductivity scaling (2DCS) curve when the mobility is scaled by r, the relative impurity-induced scattering, and the gate voltage is shifted by V s, a consequence of impurity-induced doping. This 2DCS analysis is demonstrated first in an encapsulated 2D black phosphorus multilayer at T = 100 K with charge trap densities programmed by a gate bias upon cooldown, and next in a Bi2 Se3 2D monolayer at room temperature exposed to varying concentrations of gas adsorbates. The observed scaling can be explained using a conductivity model with screened ionized impurity scatterers. The slope of the r vs. V s plot defines a disorder-charge specific scattering rate Γ q = d r / d V s equivalent to a scattering strength per unit impurity charge density: Γ q > 0 indicates a preponderance of positively charged impurities with Γ q < 0 for negatively charged. This 2DCS analysis is expected to be applicable in arbitrary 2D materials systems with tunable impurity density, which will advance 2D materials characterization and improve performance of 2D sensors and transistors.