Construction of a chiral zinc–camphorate framework for enantioselective separation. Issue 25 (15th June 2022)

• Record Type: Journal Article
• Authors: Zhu, Chengfeng; Wang, Hongzhao; Mu, Yongfei; Zhang, Ziwei; Cheng, Lanjun; Li, Tianfu; Fu, Yanming; Wu, Xiang; Li, Yougui
• Is Part Of: Dalton transactions. Volume 51:Issue 25(2022)
• Page Start: 9627
• Page End: 9631
• Publication Date: 2022-06-15
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d2dt01221a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A chiral zinc–camphorate framework with accessible chiral pores and multiple recognition sites is constructed. Acting as a recyclable chiral host, it can resolve a variety of racemic alcohols and epoxides with excellent enantioselectivities. Abstract : A chiral metal–organic framework (CMOF) with open chiral channels and multiple recognition sites is constructed from camphoric acid and a dipyridyl ligand. It can act as an efficient chiral solid adsorbent, capable of separating a variety of racemic alcohols and epoxides with excellent enantioselectivities.