Creating hierarchically porous banana paper-metal organic framework (MOF) composites with multifunctionality. (August 2022)

• Record Type: Journal Article
• Authors: Wang, Siyao; Pirzada, Tahira; Xie, Wenyi; Barbieri, Eduardo; Hossain, Oindrila; Opperman, Charles H.; Pal, Lokendra; Wei, Qingshan; Parsons, Gregory N.; Khan, Saad A.
• Is Part Of: Applied materials today. Volume 28(2022)
• Publication Date: 2022-08
• Subjects: lignocellulosic biomass -- Banana fiber -- Gas sorption -- Antibacterial matrix -- MOF-fiber composites -- VOC sensor; Materials science -- Periodicals; Materials -- Research -- Periodicals; 620.1105
• DOI: 10.1016/j.apmt.2022.101517
• Languages: English
• ISSNs: 2352-9407

Abstract

Highlights: Novel Banana paper –Metal organic framework (BP-MOF) based green composites described. BP-MOF composites are mechanically robust, flexible and have high surface area. Unique structures and synergy of BP and MOF render BP-MOF composites multifunctional. Applications as antibacterial, effective gas adsorbents and VOC sensor envisaged. Abstract: We report a robust approach to integrate metal-organic frameworks (MOF) via vapor phase synthesis on a cost-effective and mechanically durable fibrous banana paper (BP) substrate developed from lignocellulosic biomass. The unique hollow fibrous structure of BP combined with the methodology used produces MOF-fiber composites with uniform MOF distribution and enhanced functionalities, with minimal use of organic solvents. The BP-MOF composites demonstrate a high surface area of 552 m 2 /g and uniform surface growth of MOF on them. Mechanical strength and bending flexibility of the substrate is well retained after the MOF growth, while the hollow tubular nature and hierarchical porosity of the BP facilitate gas diffusion. The BP-MOF composites demonstrate strong antibacterial activity with 99.2% of E.coli destroyed within the first hour of incubation. Preliminary studies with smartphone-based volatile organic compound (VOC) sensor show enhanced 1-octen-3-ol vapor absorption on BP-MOF, indicating its potential for VOC capture and sensing. We believe that the sustainable nature and flexibility of the lignocellulosic BP substrate taken together with uniform growth of MOF on the hierarchically porous BP impart impressive attributes to these composites, which can be explored in diverse applications. Abstract : We present an innovative approach to utilize wastes from banana harvest as robust substrates for vapor-phase growth of metal-organic frameworks (MOF). Unlike traditionally used MOF-fiber composites, our samples exhibit impressive mechanical flexibility while uniform distribution of MOFs on the porous hollow fibers provide antibacterial characteristics and VOC capture ability. Image, graphical abstract .