Constructing S-scheme CeO2/CN heterojunction for high efficiency light-induced photothermal synergistic catalytic degradation of gaseous formaldehyde under visible light irradiation. Issue 3 (June 2022)

• Record Type: Journal Article
• Authors: Wang, Jianhai; Xu, Xin; Shen, Yuesong
• Is Part Of: Journal of environmental chemical engineering. Volume 10:Issue 3(2022)
• Publication Date: 2022-06
• Subjects: CN -- CeO2 -- S-scheme heterojunction -- Photothermal synergistic catalysis -- Formaldehyde degradation; Chemical engineering -- Environmental aspects -- Periodicals; Environmental engineering -- Periodicals; Chemical engineering -- Environmental aspects; Environmental engineering; Periodicals; 660.0286
• DOI: 10.1016/j.jece.2022.107436
• Languages: English
• ISSNs: 2213-2929

Abstract

Abstract: An efficient light-induced photothermal synergistic strategy was proposed to achieve efficient photocatalytic degradation of gaseous formaldehyde based on an innovative 0D/2D S-scheme CeO2 /CN heterojunction. The S-scheme photocatalyst shows excellent photocatalytic formaldehyde degradation activity under visible light irradiation, which can be attributed to the synergistic effect of the following aspects: (I) the S-scheme heterojunction: photogenerated carriers with stronger redox ability; (II) the increased interface migration channel and reduced interface contact resistance facilitated the migration and separation of photogenerated carriers; (III) light-induced photothermal effect improved the temperature of photocatalyst. The optimal photocatalytic HCHO degradation rate of the S-scheme CeO2 /CN-1:1 is 20.3, 4.7 and 1.8 times that of CN, CN-1:1 and traditional type-II CeO2 @CN-1:1, respectively. Therefore, this work not only provides an efficient strategy for elimination of formaldehyde pollutants, but also provides new ideas for the design of efficient photocatalysts for other kinds of VOCs pollutants in the future. Graphical Abstract: ga1 Highlights: The S-scheme heterojunction was successfully constructed between CeO2 and CN-1:1 by morphology and wet chemical method. The enhanced interface channels and reduced contact resistance facilitated the migration and separation of carriers. The light-induced thermal effect significantly increased the temperature of the catalyst. In the S-scheme heterojunction structure, the photogenerated carriers had stronger redox ability. The HCHO degradation rate of the S-scheme CeO2 /CN-1:1 was 20.3, 4.7, 1.8 times that of CN, CN-1:1 and type-II CeO2 /CN-1:1 .