Developments and Perspectives on Robust Nano‐ and Microstructured Binder‐Free Electrodes for Bifunctional Water Electrolysis and Beyond. Issue 23 (1st May 2022)

• Record Type: Journal Article
• Authors: Chandrasekaran, Sundaram; Khandelwal, Mahima; Dayong, Fan; Sui, Lijun; Chung, Jin Suk; Misra, R. D. K.; Yin, Peng; Kim, Eui Jung; Kim, Woong; Vanchiappan, Aravindan; Liu, Yongping; Hur, Seung Hyun; Zhang, Han; Bowen, Chris
• Is Part Of: Advanced energy materials. Volume 12:Issue 23(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-05-01
• Subjects: binder‐free electrodes -- freestanding electrodes -- HER -- OER -- water splitting; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.202200409
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract: The development of robust nano‐ and microstructured catalysts on highly conductive substrates is an effective approach to produce highly active binder‐free electrodes for energy conversion and storage applications. As a result, nanostructured electrodes with binder‐free designs have abundant advantages that provide superior electrocatalytic performance; these include more exposed active sites, large surface area, strong adhesion to substrates, facile charge transfer, high conductivity, high intrinsic catalytic activity, and fine‐tuning of its electronic nature through nanostructure modification. Notably, the interface chemistry of an electrocatalyst plays a significant role in their optimized electrocatalytic activity and stability. This review provides an overview of recent progress in nano‐ and microstructured catalysts, such as one, two, and 3D catalysts as binder‐free electrodes for electrocatalytic water splitting via the hydrogen evolution reaction and oxygen evolution reaction, and beyond. Furthermore, this review focuses on the current challenges and synthesis strategies of binder‐free electrodes, with a focus on the impact of nanostructure on their functional property relationships and enhanced bifunctional electrocatalytic performance. Finally, an outlook for their future advances in energy conversion and storage is provided. Abstract : The development of robust 1D, 2D, and 3D structured binder‐free electrodes with designed properties and architectures has led to advances in bifunctional electrocatalytic water splitting, photoelectrochemical water splitting, and photocatalysis. This review highlights the state‐of‐the‐art of binder‐free nano‐ and microstructures, from approaches based on well‐regulated fabrication to their successful application for electrocatalytic hydrogen evolution reaction/oxygen evolution reaction and photocatalysis.