Synthesis and Characterization of Pure Infinite Layer Ni+ Nickelates: LnNiO2 (Ln = La, Nd, Pr) and La3Ni2O6. (1st April 2022)

• Record Type: Journal Article
• Authors: Lokshin, Konstantin A.; Mitchell, Daniel; Lobanov, Maxim V.; Struzhkin, Viktor; Egami, Takeshi
• Is Part Of: ECS journal of solid state science and technology. Volume 11:Number 4(2022)
• Publication Date: 2022-04-01
• Subjects: Solid state chemistry -- Periodicals; Electronics -- Materials -- Periodicals; Electrochemistry -- Periodicals; 541.0421
• DOI: 10.1149/2162-8777/ac6623
• Languages: English
• ISSNs: 2162-8777

Abstract

Abstract : A synthesis method of pure low valence nickelates using a custom built H2 circulation apparatus is described. Pure infinite layer LnNiO2 (Ln = La, Nd, Pr) and La3 Ni2 O6 nickelates have been successfully prepared using this method and characterized by x-ray diffraction. Resistivity of La3 Ni2 O6 was measured as a function of temperature and pressure up to ∼2 GPa and revealed significant pressure-induced changes in both magnitude and pressure dependence of resistivity. The existence of a hidden insulator-metal transition in La3 Ni2 O6 is proposed at pressures above 100 GPa.