Oxidative cyclization of dialdehydes with alcohols and 1, 3-dicarbonyl compounds under Rh(III)/Cu(II) conditions. Issue 49 (9th December 2015)
- Record Type:
- Journal Article
- Title:
- Oxidative cyclization of dialdehydes with alcohols and 1, 3-dicarbonyl compounds under Rh(III)/Cu(II) conditions. Issue 49 (9th December 2015)
- Main Title:
- Oxidative cyclization of dialdehydes with alcohols and 1, 3-dicarbonyl compounds under Rh(III)/Cu(II) conditions
- Authors:
- Matsuda, Takanori
Suzuki, Kentaro
Abe, Shinya
Kirikae, Haruki
Okada, Noboru - Abstract:
- Abstract: For the preparation of 3-alkoxyphthalides from phthalaldehydes and alcohols, a cyclization reaction in the presence of a rhodium(III) catalyst and copper(II) salt is reported. Cyclization of phthalaldehydes also occurs with 1, 3-dicarbonyl compounds under similar conditions to produce 3-substituted phthalides in good yields. An acylrhodium(III) species might be a key intermediate in these cyclization reactions. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 71:Issue 49(2015)
- Journal:
- Tetrahedron
- Issue:
- Volume 71:Issue 49(2015)
- Issue Display:
- Volume 71, Issue 49 (2015)
- Year:
- 2015
- Volume:
- 71
- Issue:
- 49
- Issue Sort Value:
- 2015-0071-0049-0000
- Page Start:
- 9264
- Page End:
- 9270
- Publication Date:
- 2015-12-09
- Subjects:
- Phthalaldehydes -- Rhodium -- C–C bond formation -- Cyclization -- Phthalides
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2015.10.034 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 22003.xml