Copper-catalyzed C–O coupling of styrenes with N-hydroxyphthalimide through dihydroxylamination reactions. Issue 45 (11th November 2015)
- Record Type:
- Journal Article
- Title:
- Copper-catalyzed C–O coupling of styrenes with N-hydroxyphthalimide through dihydroxylamination reactions. Issue 45 (11th November 2015)
- Main Title:
- Copper-catalyzed C–O coupling of styrenes with N-hydroxyphthalimide through dihydroxylamination reactions
- Authors:
- Xia, Xiao-Feng
Zhu, Su-Li
Zhang, Danting - Abstract:
- Abstract: An efficient method of copper-catalyzed 1, 2-dihydroxylaminations of alkenes have been demonstrated under air conditions by using PhI(OAc)2 as oxidant to furnish the dioxygenated products in 20–81% yields. This provided an alternative methodology to synthesis of dioxygenated products, which were easily transformed into diols under the reductive conditions. Furthermore, a free-radical addition mechanism was proposed in this transformation. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 71:Issue 45(2015)
- Journal:
- Tetrahedron
- Issue:
- Volume 71:Issue 45(2015)
- Issue Display:
- Volume 71, Issue 45 (2015)
- Year:
- 2015
- Volume:
- 71
- Issue:
- 45
- Issue Sort Value:
- 2015-0071-0045-0000
- Page Start:
- 8517
- Page End:
- 8520
- Publication Date:
- 2015-11-11
- Subjects:
- Copper-catalyzed -- 1, 2-Dihydroxylamination -- Styrenes -- N-Hydroxyphthalimide -- Radical addition
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2015.09.040 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 21999.xml