Concise total synthesis of (±)-pisiferin. Issue 49 (9th December 2015)
- Record Type:
- Journal Article
- Title:
- Concise total synthesis of (±)-pisiferin. Issue 49 (9th December 2015)
- Main Title:
- Concise total synthesis of (±)-pisiferin
- Authors:
- Li, Yulong
Li, Liqi
Guo, Yueming
Xie, Zhixiang - Abstract:
- Abstract: A concise total synthesis of (±)-pisiferin has been accomplished from commercially available compounds α-cyclocitral (9 ) and 4-bromo-2-isopropylphenol (10 ) via Suzuki coupling and F–C alkylation as key reaction in five steps with an overall yield of 22%. The feature of this concise synthesis is a convergent strategy coupled by Suzuki reaction. This work not only provides a strategy to approach the total synthesis of pisiferin itself but also serves as an additional correlation origin to which many related icetaxane-type diterpenes can be referred. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 71:Issue 49(2015)
- Journal:
- Tetrahedron
- Issue:
- Volume 71:Issue 49(2015)
- Issue Display:
- Volume 71, Issue 49 (2015)
- Year:
- 2015
- Volume:
- 71
- Issue:
- 49
- Issue Sort Value:
- 2015-0071-0049-0000
- Page Start:
- 9282
- Page End:
- 9286
- Publication Date:
- 2015-12-09
- Subjects:
- Icetaxane-type diterpenes -- Total synthesis -- Pisiferin -- Suzuki coupling -- F–C alkylation
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2015.10.032 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 22003.xml