Design of sandwich structure conductive polypropylene/styrene‐butadiene‐styrene triblock copolymer/carbon black composites with inherent morphological tunability. Issue 24 (8th February 2021)

• Record Type: Journal Article
• Authors: Zhou, Zichen; Yang, Zhangbin; Sun, Haoxuan; Zhang, Jun
• Is Part Of: Journal of applied polymer science. Volume 138:Issue 24(2021)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2021-02-08
• Subjects: blends -- carbon black -- conductive polymer composites -- double percolation -- sandwich structure; Polymers -- Periodicals; Polymerization -- Periodicals; 668.9
• DOI: 10.1002/app.50567
• Languages: English
• ISSNs: 0021-8995

Abstract

Abstract: The insulator‐conductor transition of conductive polymer composites (CPCs) can be ascribed to the fabrication of conductive networks, and the morphology of conductive networks plays a significant role in the electrical conductivity. This study presents CPCs with inherent morphology tunability which can be controlled by kinetic methods (i.e., mixing procedures and sequences, and polymer melt viscosity). Polypropylene (PP)/styrene‐butadiene‐styrene block copolymer (SBS) (50/50, in volume)/10 phr (parts per hundred of the polymer matrix) conductive carbon black (CB) composites prepared by different compounding sequences (PP/CB composites mixed with SBS, SBS/CB composites mixed with PP, and PP/SBS blend mixed with CB) are named as PC10 S, SC10 P, and PSC10 . With the difference between the phase morphologies, distribution, and dispersion of CB, the PP/SBS/CB composites realize seven orders of magnitude difference in resistivity. The volume resistivity ( ρ v ) of PC10 S SC10 P and PSC10 are 1.57 × 10 1, 1.68 × 10 2, and 4.88 × 10 8 Ω m, respectively. Abstract :