Additive-free selective methylation of secondary amines with formic acid over a Pd/In2O3 catalyst. Issue 1 (13th December 2021) - Genre, Caroline
Abstract : Formic acid is the sole carbon and hydrogen source in the additive-free catalytic methylation of amines. Abstract : Formic acid is used as the sole carbon and hydrogen source in the methylation of aromatic and aliphatic amines to methylamines. The reaction proceeds via a formylation/transfer hydrogenation pathway over a solid Pd/In2 O3 catalyst without the need for any additive.