A novel strategy to reduce the viscosity of cellulose-ionic liquid solution assisted by transition metal ions. (15th March 2021)

• Record Type: Journal Article
• Authors: Fan, Zhaosheng; Chen, Jianbo; Sun, Suqin; Zhou, Qun
• Is Part Of: Carbohydrate polymers. Volume 256(2021)
• Publication Date: 2021-03-15
• Subjects: Cellulose solution -- Ionic liquids -- Viscosity modulate -- Copper chloride; Polysaccharides -- Periodicals; Polysaccharides -- Periodicals; Polysaccharides -- Périodiques; Electronic journals; 547.78
• DOI: 10.1016/j.carbpol.2020.117535
• Languages: English
• ISSNs: 0144-8617

Abstract

Graphical abstract: Highlights: Viscosity of cellulose-ionic liquid was reduced based on coordination chemistry. Cellulose fibers production efficiency was hugely promoted. The regenerated cellulose property was not affected by the dissolving CuCl2 . Surface and diameter of cellulose fiber were improved. Abstract: The high viscosity of ionic liquids, even at relatively high temperatures, can greatly affect the production of cellulose fibers through the wet-spinning process. The high viscosity mainly by due to the hydrogen bond interaction between the cations and anions of ionic liquids. It is possible to reduce the viscosity by modulating the hydrogen bond interaction. In the present work, copper chloride (CuCl2 ) was dissolved in 1-butyl-3-methylimidazolium chloride ([Bmim]Cl)-cellulose solution, followed by the formation of a complex with the chloride anions by converting it to [CuCl4 ] 2− anion. Through this strategy, the extrusion velocity of the solution improved, and the produced fibers obtained smoother surfaces and shrunken diameters.