AC magnetic field enhancement oxygen evolution reaction of bimetallic metal-organic framework. (19th May 2022)

• Record Type: Journal Article
• Authors: Chen, Hui-hui; Zheng, Hang-bo; Yang, Tong-hui; Yue, Song; Gao, Peng-zhao; Liu, Xiao-pan; Xiao, Han-ning
• Is Part Of: International journal of hydrogen energy. Volume 47:Number 43(2022)
• Page Start: 18675
• Page End: 18687
• Publication Date: 2022-05-19
• Subjects: Bimetallic metal-organic framework -- Oxygen evolution reaction -- AC magnetic Field; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2022.04.014
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: Cost-effective oxygen evolution reaction (OER) electrocatalysts play a key role in electrocatalytic water splitting process. Here, a facile and scalable strategy was applied to synthesize the bimetallic metal-organic frameworks (MOFs) with high OER activity, and the effects of AC magnetic field on OER was also investigated. Results shows that the bimetallic MOFs (Co0.4 Ni0.6 -MOF-74) exhibited a three-dimensional flower-like morphology, and possessed a higher BET specific area of 905.39 m 2 g −1 as well as a smaller median pore size of 0.49 nm as compared to single metal MOFs; It owned a lowest overpotential of 314 mV at 10 mA cm −2 and Tafel slope of 79.39 mV dec −1, both are much lower than these of single metal MOFs, being due to the high specific area and more active sites derived from the distorted crystal structure; When AC magnetic field strength equaled to 5.50 mT, overpotential at 10 mA cm −2 for Co0.4 Ni0.6 -MOF-74 reached minimum value of 201 mV, reduced by about 36% as compared to that without magnetic field, indicated that AC magnetic field could greatly improve OER process. These improvements resulted from the spin polarization effect, magnetohydrodynamic (MHD) convection and improved active point temperature. Highlights: Co0.4 Ni0.6 -MOF-74 owned a lowest OER overpotential of 314 mV at 10 mA cm −2 . η 10 of Co0.4 Ni0.6 -MOF-74 is reduced by up to 36% under AC magnetic field. Spin polarization, magnetic heating effect and MHD convection improved OER activity.