Copolymerization of Sulfur Chains with Vinyl Functionalized Metal−Organic Framework for Accelerating Redox Kinetics in Lithium−Sulfur Batteries (Adv. Energy Mater. 21/2022). Issue 21 (2nd June 2022)

• Record Type: Journal Article
• Authors: Zeng, Qinghan; Li, Xin; Gong, Wei; Guo, Sijia; Ouyang, Yuan; Li, Dixiong; Xiao, Yingbo; Tan, Chao; Xie, Lin; Lu, Haibin; Zhang, Qi; Huang, Shaoming
• Is Part Of: Advanced energy materials. Volume 12:Issue 21(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-06-02
• Subjects: metal‐organic frameworks -- lithium‐sulfur batteries -- shuttle effect -- copolymerization -- redox kinetics; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.202270088
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract : MOF/S Composite Cathodes In article number 2104074, Qi Zhang, Shaoming Huang and co‐workers propose an efficient strategy to elaborate sulfur cathodes by copolymerization between MOFs and sulfur chains. The radical reaction mechanism of the cathode derived accelerated polysulfides conversion restrains the shuttle effect and improves battery performance compared to traditional MOF/S composite cathodes at both low and high sulfur loadings.