A highly selective and sensitive fluorescent light-up probe for rapid detection of mercury ions in aqueous solution. (22nd June 2022)

• Record Type: Journal Article
• Authors: Bao, Guangbo; Zhou, Baocheng; Han, Yifeng
• Is Part Of: Tetrahedron letters. Volume 100(2022)
• Publication Date: 2022-06-22
• Subjects: Fluorescent probe -- Desulfurization reaction -- Mercury ions -- Solid optical sensor; Chemistry, Organic -- Periodicals; 547.005
• DOI: 10.1016/j.tetlet.2022.153887
• Languages: English
• ISSNs: 0040-4039

Abstract

Graphical abstract: Highlights: A new water-soluble fluorescent probe for Hg 2+ has been designed and developed. The probe exhibits high sensitivity and fast kinetics for Hg 2+ ions in aqueous solution. The probe can conveniently use agar gel to detect Hg 2+ visually. Abstract: Due to its complex biological toxicity, mercury ions can cause various neurological diseases and even death. Therefore, developing a rapid and efficient mercury ions analysis method is of great significance. In this study, we designed a new water-soluble fluorescent chemical sensor, Hg535, which can sensitively detect mercury ions in an aqueous solution. Based on the specific mercury-mediated desulfurization reaction, the probe exhibits high selectivity for mercury ions, excellent sensitivity, significant Stokes shift (108 nm), and fast kinetics (within 15 s), with a low detection limit (1.66 ppb). Finally, agar gels based on the probe Hg535 were fabricated, which could act as a solid optical sensor to conveniently and efficiently detect Hg 2+ .