The effect of reactor scale on biochars and pyrolysis liquids from slow pyrolysis of coffee silverskin, grape pomace and olive mill waste, in auger reactors. (1st July 2022)

• Record Type: Journal Article
• Authors: del Pozo, Cristina; Rego, Filipe; Puy, Neus; Bartrolí, Jordi; Fàbregas, Esteve; Yang, Yang; Bridgwater, Anthony V.
• Is Part Of: Waste management. Volume 148(2022)
• Page Start: 106
• Page End: 116
• Publication Date: 2022-07-01
• Subjects: Biochar -- Pyrolysis liquid -- Agricultural wastes -- Pyrolysis auger reactor -- Scale-up; CSS Coffee Silverskin -- GP Grape Pomace -- OMW Olive Mill Waste -- NAP Non-Aqueous Phase of the pyrolysis liquid -- AP Aqueous Phase of the pyrolysis liquid; Hazardous wastes -- Periodicals; Refuse and refuse disposal -- Periodicals; 363.728
• DOI: 10.1016/j.wasman.2022.05.023
• Languages: English
• ISSNs: 0956-053X

Abstract

Highlights: No major difference was observed in biochars, regardless of auger scale. Existing biochar research could be reproduced in other auger reactors. Pyrolysis liquid composition highly depended on the vapor residence time. Pyrolysis products from common agricultural wastes were compared. Abstract: Several studies have addressed the potential biorefinery, through small-scale pyrolysis, of coffee silverskin (CSS), grape pomace (GP) and olive mill waste (OMW), which are respectively the main solid residues from coffee roasting, wine making and olive oil production processes. However, increasing the scale of reactor to bring these studies to an industrial level may affect the properties, and hence applications, of the resulting products. The aim of this study is therefore to perform pilot scale experiments to compare and verify the results of analytical study (TGA) and bench scale reactor runs, in order to understand the fundamental differences and create correlations between pyrolysis runs at different scales. To this end, pyrolysis liquids and biochars from the slow pyrolysis of CSS, GP and OMW, performed using different scale auger reactors (15 kg/h and 0.3 kg/h), have been analysed (TGA, pH, density, proximate and ultimate analyses, HHV, FTIR, GCMS) and compared. The results showed no major differences in biochars when the temperature and the solid residence time were fixed. However, regarding pyrolysis liquids, compounds from the lab reactor were more degraded than pilot plant ones, due to, in this case, the vapour residence time was longer. Regarding the properties of the pyrolysis products, GP 400 °C biochars showed the best properties for combustion; CSS biochars were especially rich in nitrogen, and 400 °C GP and OMW pyrolysis liquids showed the highest number of phenolics. Hence, this study is considered a first step towards industrial scale CSS, GP and OMW pyrolysis-based biorefinery.