Analytical perspective and environmental remediation potentials of magnetic composite nanosorbents. (October 2022) - Zhang, Shizhong
Abstract: The synthesis and application of magnetic nanosorbents to remove emerging pollutants have been considered the best environmental remediation and sustainability option. Incorporating magnetism shortens the treatment time and allows the sorbent to be recovered quickly using external magnetic with many cycles. The implementation of magnetic solid-phase extraction (MSPE) using magnetic materials of different shapes, sizes, and surface morphology can be a valuable tool in applying materials to prepare analytical samples. In MSPE applications, materials with strong magnetic domain can be used as precursors for constructing magnetic composite as a promising sorbent. This article focuses on the most recent and exceptional applications of magnetic adsorbents for preconcentration and removal purposes. Magnetic adsorbents, such as nanoparticles (NPs), foam, sponges, nanocomposites, hydrogels, and beads with multifunctional attributes have been comprehensively studied in terms of preparation procedures, limitations, advantages, and interactions between pollutants and magnetic composites. The role of magnetic sorbents in sample preparation methods, such as simple solid-phase extraction and microextraction, as well as sorptive extraction using a stir bar, was also examined. The use of magnetic adsorbents with analytical techniques, such as solid-phase extraction and solid-phase microextraction improves the method for preparing samples concerning the influential role of magnetic adsorbents. Towards the end, promising features and future outlook are also directed. Graphical abstract: Image 1 Highlights: Recalcitrant pollutants present a serious threat to environmental sustainability. Magnetic nanosorbents for preconcentration and mitigation of environmental pollutants. Preparation strategies, limitations, and interactive mechanisms between pollutants and magnetic composites. Role of magnetic sorbents in sample preparation methods and sorptive extraction was examined.