Observation of the Reaction Intermediates of Methanol Dehydrogenation by Cationic Vanadium Clusters. Issue 9 (4th January 2021)

• Record Type: Journal Article
• Authors: Hou, Gao‐Lei; Faragó, Endre; Buzsáki, Dániel; Nyulászi, László; Höltzl, Tibor; Janssens, Ewald
• Is Part Of: Angewandte Chemie international edition. Volume 60:Issue 9(2021)
• Page Start: 4756
• Page End: 4763
• Publication Date: 2021-01-04
• Subjects: low-pressure collision cell -- mass spectrometry -- methanol dehydrogenation -- reaction intermediates -- vanadium clusters; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.202011109
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: A mass spectrometric study of the reactions of vanadium cationic clusters with methanol in a low‐pressure collision cell is reported. For comparison, the reaction of methanol with cobalt cationic clusters was studied. For vanadium, the main reaction products are fully dehydrogenated species, and partial dehydrogenation and non‐dehydrogenation species are observed as minors, for which the relative intensities increase with cluster size and also at low cluster source temperature cooled by liquid nitrogen; no dehydrogenation products were observed for cobalt clusters. Quantum chemical calculations explored the reaction pathways and revealed that the fully dehydrogenation products of the reaction between V n + and methanol are V n (C)(O) +, in which C and O are separated owing to the high oxophilicity of vanadium. The partial dehydrogenation and non‐dehydrogenation species were verified to be reaction intermediates along the reaction pathway, and their most probable structures were proposed. Abstract : Strikingly different reactivity of vanadium and cobalt cationic clusters towards methanol in a low‐pressure collision cell is observed by mass spectrometry. Metastable or kinetically trapped reaction intermediates of the methanol reaction with vanadium cationic clusters are verified, and their structures are proposed by exploring the reaction pathways using density functional theory calculations.