Trinuclear anionic gold clusters bridged by dialkylsilylene and dialkylgermylene. Issue 47 (20th May 2022)

• Record Type: Journal Article
• Authors: Li, Yinhuan; Zhen, Guorong; Huang, Lu; Zhang, Rong; Wang, Liliang; Qi, Fan; Kira, Mitsuo; Li, Zhifang
• Is Part Of: Chemical communications. Volume 58:Issue 47(2022)
• Page Start: 6705
• Page End: 6708
• Publication Date: 2022-05-20
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d2cc02054h
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Herein, we report the synthesis, structural characterization, and density functional theory (DFT) calculations of trinuclear anionic gold clusters 3a and 3b ligated by dialkylsilylene (1a ) and dialkylgermylene (1b ), respectively. Abstract : While the chemistry of gold clusters has been developed rapidly, the knowledge of trinuclear gold clusters with low-valent gold remains scarce. Herein, we report the synthesis, structural characterization, and density functional theory (DFT) calculations of trinuclear anionic gold clusters 3a and 3b ligated by dialkylsilylene (1a ) and dialkylgermylene (1b ), respectively.