Efficient blue CsPb(Br–Cl)3 nanoparticles enabled by strontium halide and amine halide synergetic optimization. Issue 22 (27th May 2022)

• Record Type: Journal Article
• Authors: Guo, Runda; Zhang, Weizhuo; Li, Xin; Lian, Linyuan; Chen, Hongting; Peng, Chencheng; Sun, Liang; Liu, Shiyuan; Zhang, Jianbing; Wang, Lei
• Is Part Of: Journal of materials chemistry. Volume 10:Issue 22(2022)
• Page Start: 8815
• Page End: 8823
• Publication Date: 2022-05-27
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d2tc00796g
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : Blue emitting CsPb(Br–Cl)3 perovskite nanoparticles (NPs) play an important role in optoelectronic applications. Abstract : Blue emitting CsPb(Br–Cl)3 perovskite nanoparticles (NPs) play an important role in optoelectronic applications. However, the synthesis of stable blue perovskite NPs with excellent photoluminescence quantum yield (PLQY) is still challenging. Here, a new strategy of conveniently using strontium halides and amine halides for simultaneous doping and surface passivation of CsPb(Br–Cl)3 perovskite NPs is proposed. Through experimental studies and calculations, it is found that divalent Sr 2+ cations can partly replace the B-site Pb 2+ ions in the lattice structure of perovskite NPs and cause a slight lattice contraction, not only passivating the defects but also providing chances for bluer NPs. As a result, the deep-blue CsPb(Br–Cl)3 perovskite NPs with PL emission centered at 455 nm and a high PLQY of 96% were obtained. In addition, a white light-emitting device (WLED) with the NPs as an emissive layer exhibited a maximum power efficiency of 76 lm W −1 with Commission International de L'Eclairage (CIE) coordinates of (0.33, 0.34). These findings provide fundamental insights into the excited state dynamics of colloidal cesium lead halide (CsPbX3 ) perovskite NPs that can be used as components of LEDs for practical applications.