N, N-Dimethylformamide-stabilized ruthenium nanoparticle catalyst for β-alkylated dimer alcohol formation via Guerbet reaction of primary alcohols. Issue 26 (6th June 2022)

• Record Type: Journal Article
• Authors: Nagata, Tatsuki; Okada, Kanji; Kondo, Ryota; Toyao, Takashi; Shimizu, Ken-ichi; Suzuki, Takeyuki; Obora, Yasushi
• Is Part Of: RSC advances. Volume 12:Issue 26(2022)
• Page Start: 16599
• Page End: 16603
• Publication Date: 2022-06-06
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/d2ra02381d
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : N, N -Dimethylformamide-stabilized Ru nanoparticles (NPs) provide a highly efficient catalyst for the Guerbet reaction of primary alcohols under solvent-free conditions and without the use of external ligands. Abstract : N, N -Dimethylformamide-stabilized Ru nanoparticles (NPs) provide a highly efficient catalyst for the Guerbet reaction of primary alcohols. DMF-modified Ru NPs were synthesized, and characterized by transition electron microscopy, and X-ray absorption spectroscopy, X-ray photoelectronspectroscopy, and Fourier-transform infrared spectroscopy. The Ru NP catalyst was highly durable during catalytic reactions under external additive/solvent-free conditions.