Pulsed-laser deposition and photocatalytic activity of pure rutile and anatase TiO2 films: Impact of single-phased target and deposition conditions. (August 2022)

• Record Type: Journal Article
• Authors: Cesaria, M.; Scrimieri, L.; Torrisi, A.; Quarta, G.; Serra, A.; Manno, D.; Caricato, A.P.; Martino, M.; Calcagnile, L.; Velardi, L.
• Is Part Of: Vacuum. Volume 202(2022)
• Publication Date: 2022-08
• Subjects: Vacuum -- Periodicals; 621.55
• DOI: 10.1016/j.vacuum.2022.111150
• Languages: English
• ISSNs: 0042-207X

Abstract

Abstract: Titanium dioxide is a technologically interesting material in many applicative fields that, however, exhibits critical aspects in terms of phase purity and synthesis/growth conditions. The presented work deals with the deposition, in vacuum, of single-phase rutile and anatase titania films by excimer laser ablation (λ = 248 nm) of anatase and rutile targets. Post-deposition thermal treatment at 450 °C in air was applied to drive the crystalline evolution of the as-deposited films, limit oxygen desorption and avoid changes in the polymorph phase. Unlike the typical use of oxygen as a background gas and Ti target in pulsed laser deposition of TiO2, our setting vacuum background atmosphere not only allows to relate the final phase of the film directly to the target phase but also to rule out phase transitions and mixed-phase, by the interplay between post-growth temperature and limited oxygen desorption. Herein, we study and discuss how the ablation process impacts on and determines film composition and morphology. The discussed influence of the target phase on the optical, morphological and photocatalysis properties of the titania films points out good performances of our samples and the importance to tune deposition to obtain the titania polymorph phase more suitable for specific applications. Highlights: TiO2 anatase and rutile films were produced by PLD in vacuum without oxygen. The final phase of the film is directly related to the target phase, without phase transitions or mixed-phases. No formation oxygen vacancies-related defects acting as traps of photogenerated electrons. The photocatalytic activity of the TiO2 films was observed under UV irradiations. Anatase and rutile films differ in chemical, physical and optical properties, making them suitable for specific applications.