Template-based textural modifications of polymeric graphitic carbon nitrides towards waste water treatment. (September 2022)

• Record Type: Journal Article
• Authors: Azhar, Umair; Bashir, Muhammad Sohail; Babar, Muhammad; Arif, Muhammad; Hassan, Afaq; Riaz, Asim; Mujahid, Rana; Sagir, Muhammad; Suri, Saadat Ullah Khan; Show, Pau Loke; Chang, Jo-Shu; Khoo, Kuan Shiong; Mubashir, Muhammad
• Is Part Of: Chemosphere. Volume 302(2022)
• Publication Date: 2022-09
• Subjects: Wastewater treatment -- g-C3N4 -- Soft templating methodl textural modificationl -- Graphitic carbon nitride; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2022.134792
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: The composite materials based on graphitic carbon nitrides (g-C3 N4 ) are remarkably better semiconductors, but the inherent photocatalytic performance in its generic synthesis form is not up to the mark. Eminence efforts have been made to improve its performance and photocatalytic efficiencies. Recently, extensive investigations have been performed to develop their texturally modified and highly porous structures to get around the big flaws of bulk g-C3 N4 . One significant disadvantage is the increase in the polycondensation while preparation at 550 °C results in g-C3 N4 materials with restricted specific surface area (SSA) (<10 m 2 /g) and no textured pores. Textural modification has emerged as an efficient and progressive way to improve optical and electronic characteristics. The final texture and shape of CN are influenced by the precursor's interaction with the template. Researchers are interested in developing CN materials with high SSA and changeable textural properties (pore volume and pore size). Based on the literature review it is concluded that the soft templating approach is relatively simple, and straightforward to induce textural changes in the g-CN type materials. This review focused on improving the textural properties of bulk g-C3 N4 via templating method, and the major advances in the modified g-C3 N4 materials for the treatment of wastewater. The procedures and mechanisms of numerous approaches with varying morphologies are thoroughly explained. Graphical abstract: Image 1 Highlights: Surfactants as soft templates to improve textural properties. Ionic liquids as soft template to modify G-C3 N4 properties. Challenges of self-templating technique to modify textural properties. Application of G-C3 N4 in waste water treatment.