Beyond a Linker: The Role of Photochemistry of Crosslinkers in the Direct Optical Patterning of Colloidal Nanocrystals. (5th April 2022)

• Record Type: Journal Article
• Authors: Lu, Shaoyong; Fu, Zhong; Li, Fu; Weng, Kangkang; Zhou, Likuan; Zhang, Lipeng; Yang, Yuchen; Qiu, Hengwei; Liu, Dan; Qing, Wenyue; Ding, He; Sheng, Xing; Chen, Menglu; Tang, Xin; Duan, Lian; Liu, Wenyong; Wu, Longjia; Yang, Yixing; Zhang, Hao; Li, Jinghong
• Is Part Of: Angewandte Chemie. Volume 134:Number 23(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-04-05
• Subjects: Optoelectronic Devices -- Photo-Patterning of Nanocrystals -- Photochemistry -- Photocrosslinkers -- Quantum Dots; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.202202633
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Surface chemistry mediated direct optical patterning represents an emerging strategy for incorporating colloidal nanocrystals (NCs) in integrated optoelectronic platforms including displays and image sensors. However, the role of photochemistry of crosslinkers and other photoactive species in patterning remains elusive. Here we show the design of nitrene‐ and carbene‐based photocrosslinkers can strongly affect the patterning capabilities and photophysical properties of NCs, especially quantum dots (QDs). Their role beyond physical linkers stems from structure‐dictated electronic configuration, energy alignment and associated reaction kinetics and thermodynamics. Patterned QD layers with designed carbene‐based crosslinkers fully preserve their photoluminescent and electroluminescent properties. Patterned light emitting diodes (QLEDs) show a maximum external quantum efficiency of ≈12 % and lifetime over 4800 h, among the highest for reported patterned QLEDs. These results would guide the rational design of photoactive species in NC patterning and create new possibilities in the monolithic integration of NCs in high‐performance device platforms. Abstract : Nitrene‐ and carbene‐based photocrosslinkers enable direct optical patterning of colloidal nanocrystals via similar mechanism. However, their photochemistry drastically affects the patterning capabilities and photophysical properties of patterned nanocrystals. Understanding their roles beyond physical linkers guides the rational design of crosslinkers for high‐performance patterned NC layers and devices, such as electroluminescent QLEDs.