Nitrate‐to‐Ammonia Conversion on Ru/Ni Hydroxide Hybrid through Zinc‐Nitrate Fuel Cell. Issue 21 (1st May 2022)

• Record Type: Journal Article
• Authors: Zhou, Fengling; Sun, Chenghua
• Is Part Of: Small. Volume 18:Issue 21(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-05-01
• Subjects: ammonia -- nickel -- nitrate reduction -- ruthenium -- zinc‐nitrate fuel cells; Nanotechnology -- Periodicals; Nanoparticles -- Periodicals; Microtechnology -- Periodicals; 620.5
• DOI: 10.1002/smll.202200436
• Languages: English
• ISSNs: 1613-6810

Abstract

Abstract: The fuel cell is a basic device to generate electricity from chemical fuels. It is often operated with oxygen as the oxidizing agent, but its sluggish reduction has become a key challenge. Herein, a conceptual oxygen‐free design is demonstrated, namely a zinc‐nitrate fuel cell, which converts nitrate waste into valuable ammonia and generates electricity simultaneously. The cell is constructed with zinc foil as the anode and ruthenium (Ru) nanoparticles loaded on nickel foam as the cathode. Catalyzed by Ru/Ni hydroxide hybrid, the reaction rate of 384 mmol h –1 mgRu –1 (1.4 × 10 –6 ± 0.1 × 10 –6 mol s –1 cm –2 ) and Faradic efficiency (FENH3 = 97% ± 2%) at −0.6 V versus reverse hydrogen electrode are achieved for nitrate‐to‐ammonia conversion. During ammonia production, such zinc‐nitrate fuel cell can further deliver a maximum power density of 51.5 mW cm –2 (0.25 cm 2 electrode) and 23.3 mW cm –2 (1 cm 2 electrode), keeping ultrahigh Faradic efficiency (97% ± 4% at 40 mA cm –2 ) after long tests. Abstract : A highly active Ru/Ni hydroxide hybrid for nitrate‐to‐ammonia conversion is synthesized by electrodeposition and exhibits an impressive ammonia yield rate of 384 mmol h −1 mgRu −1 (1.4 × 10 –6 ±0.1 × 10 –6 mol s −1 cm −2 ) and Faradic efficiency (FENH3 = 97% ± 2%). A zinc‐nitrate fuel cell based Ru/Ni hydroxide hybrid generates ammonia from nitrate and simultaneously delivers a maximum power density of 51.5 mW cm −2 .