Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones. Issue 43 (6th May 2022)
- Record Type:
- Journal Article
- Title:
- Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones. Issue 43 (6th May 2022)
- Main Title:
- Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones
- Authors:
- Romero, R. Martin
Thyagarajan, Neethu
Hellou, Nora
Chauvier, Clément
Godou, Timothé
Anthore-Dalion, Lucile
Cantat, Thibault - Abstract:
- Abstract : The transfer hydrosilylation of ketones with silyl formates was unlocked, relying on the crucial role of a cooperative PN H P ligand. Abstract : A transfer hydrosilylation of ketones employing silyl formates as hydrosilane surrogates under mild conditions is presented. A total of 24 examples of ketones have been successfully converted to their corresponding silyl ethers with 61–99% yields in the presence of a PN H P-based ruthenium catalyst and silyl formate reagent. The crucial role of the ligand for the transformation is demonstrated.
- Is Part Of:
- Chemical communications. Volume 58:Issue 43(2022)
- Journal:
- Chemical communications
- Issue:
- Volume 58:Issue 43(2022)
- Issue Display:
- Volume 58, Issue 43 (2022)
- Year:
- 2022
- Volume:
- 58
- Issue:
- 43
- Issue Sort Value:
- 2022-0058-0043-0000
- Page Start:
- 6308
- Page End:
- 6311
- Publication Date:
- 2022-05-06
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d2cc00666a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 21740.xml