A series of asymmetric and symmetric porphyrin derivatives: one-pot synthesis, nonlinear optical and optical limiting properties. (13th August 2021)

• Record Type: Journal Article
• Authors: Bao, Changjiang; Li, Yanwei; Li, Yanhui; Si, Zhenjun; Zhang, Yanru; Chen, Changshun; Wang, Lei; Duan, Qian
• Is Part Of: New journal of chemistry. Volume 45:Number 35(2021)
• Page Start: 16030
• Page End: 16038
• Publication Date: 2021-08-13
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/d1nj02632a
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : In this work, a series of asymmetric and symmetric porphyrin derivatives (structure types: A4, A3 B1, trans -A2 B2, cis -A2 B2, A1 B3, and B4 ) have been synthesized via a one-pot method and characterized to identify their structures and properties. Abstract : In this work, a series of asymmetric and symmetric porphyrin derivatives (structure types: A4, A3 B1, trans -A2 B2, cis -A2 B2, A1 B3, and B4 ) have been synthesized via a one-pot method and characterized by TLC, HPLC, FT-IR, 1 H-NMR and UV-Vis to identify their structures and properties. The porphyrin derivatives with trans -A2 B2 and cis -A2 B2 structures are visually distinguished via single-crystal X-ray diffraction; the crystal morphology of trans -A2 B2 is a needle-like structure. All porphyrin derivatives (I–VI ) have excellent nonlinear optical (NLO) and optical limiting (OL) properties, and are investigated using the standard Z -scan technique. Porphyrin derivative III exhibits the maximum nonlinear absorption, nonlinear refraction coefficients and optical limitation threshold, and the values are 3.7 × 10 −9 m W −1, −17 × 10 −17 m 2 W −1 and 0.11 J cm −2, respectively. The results demonstrate that the introduction of different substituent numbers (mono-, di- and tri-, tetra-) and substituent sites ( trans -A2 B2 and cis -A2 B2 ) in the porphyrins could influence the NLO and OL properties. Structure regulation of porphyrin can lead to the adjustment of NLO and OL properties, and affect its practical NLO application in the future.