Direct microscopic evidence of shear induced graphitization of ultrananocrystalline diamond films. (July 2021)

• Record Type: Journal Article
• Authors: Ganesan, K.; Rani, Revati; Mathews, Tom; Dhara, S.
• Is Part Of: Carbon trends. Number 4(2021)
• Publication Date: 2021-07
• Subjects: Ultrananocrystalline diamond -- Tribofilms -- Friction -- Wear -- Atomic force microscopy -- Nanotribology; Carbon -- Periodicals; Carbon composites -- Periodicals; Carbon; Carbon composites; Periodicals; 620.193
• DOI: 10.1016/j.cartre.2021.100078
• Languages: English
• ISSNs: 2667-0569

Abstract

Highlights: We demonstrate evidence for growth of large network of graphene layers on tribofilm Evolution of graphene layers occurs through shear induced graphitization of UNCD Newly born graphene layers offer ultralow friction and wear resistance of UNCD Microstructure of graphene layers plays a crucial role on tribology of UNCD films AFM based nanotribology helps in understanding friction and wear at nanometer-scale Abstract: The origin of ultralow friction and high wear resistance in ultrananocrystalline diamond (UNCD) films is still under active debate because of the perplexed tribochemistry at the sliding interface. Herein, we report a comparative study on surface topography and nanoscale friction of tribofilms, in wear tracks of two sets of UNCD films having different structural characteristics. Despite both the films display ultralow coefficient of friction, the UNCD films grown under Ar atmosphere (UNCDAr ) exhibit a high wear resistance while the wear rate is higher for the films grown in N2 (UNCDN ). Frictional force microscopic (FFM) investigations clearly reveal the manifestation of shear induced graphitization on both the films. However, the wear track of UNCDAr films have a large network of a few layer graphene (FLG) structures over the amorphous carbon tribofilms while only isolated clusters of FLG structures are present in the wear track of UNCDN films. Here, we demonstrate the direct micro-/nanoscopic evidence for the formation of large network of ~ 0.8 - 6 nm thick FLG structures, as a consequence of shear induced graphitization and discuss their decisive role in ultralow friction and wear. Graphical abstract: Image, graphical abstract