Study on wax precipitation characteristics of wax deposit in pipes. (22nd December 2019)

• Record Type: Journal Article
• Authors: Gao, Xuedong; Huang, Qiyu; Zhang, Xun; Li, Weidong; Ren, Yijie; Wang, Junfang
• Is Part Of: Canadian journal of chemical engineering. Volume 98:Number 5(2020)
• Page Start: 1202
• Page End: 1210
• Publication Date: 2019-12-22
• Subjects: crude oil -- flow condition -- wax deposit -- wax precipitation characteristics; Chemical engineering -- Periodicals; Technology -- Periodicals; 660.05
• DOI: 10.1002/cjce.23690
• Languages: English
• ISSNs: 0008-4034

Abstract

Abstract: Wax deposit properties are a significant concern in pipeline pigging during waxy crude oil transportation. In the present work, the impacts of flow conditions and oil properties on the wax precipitation characteristics of wax deposits are investigated. A flow loop apparatus was developed to conduct wax deposition experiments using four crude oils collected from different field pipes. The differential scanning calorimetry (DSC) technique was employed to observe the wax precipitation characteristics of crude oil and wax deposit. The results show that the wax content and the wax appearance temperature (WAT) of the deposits increase with shear stress and radial temperature gradient, and decrease with radial wax molecule concentration gradient near the pipe wall. The DSC tests on the wax deposits revealed that the deposit wax content is strongly correlated to the oil wax content. Furthermore, an empirical correlation was developed to predict the wax content and the WAT of the wax deposit. Verification of the empirical correlation using the different oils indicated that the average relative error of the wax content prediction and average absolute error of WAT prediction were 13.2% and 3.6°C, respectively.