Butanol production via vacuum fermentation: An economic evaluation of operating strategies. (23rd February 2019)

• Record Type: Journal Article
• Authors: Grisales Díaz, Víctor Hugo; von Stosch, Moritz; Willis, Mark J.
• Is Part Of: Chemical engineering science. Volume 195(2019)
• Page Start: 707
• Page End: 719
• Publication Date: 2019-02-23
• Subjects: Butanol production -- Heat pump -- Dynamic modelling -- Scheduling -- Economic optimisation -- Batch, fed-batch, continuous operation; Chemical engineering -- Periodicals; Génie chimique -- Périodiques; Chemical engineering; Periodicals; Electronic journals; 660
• DOI: 10.1016/j.ces.2018.10.016
• Languages: English
• ISSNs: 0009-2509

Abstract

Highlights: ABE fermentation under vacuum (batch, fed-batch and continuous operation). Selection of the optimum operating mode via economic optimisation. The scheduling of the dynamic reactors minimised the size of the heat-pump system. Fed-batch operation is the most economical choice. Continuous operation has the highest productivity and energy consumption. Abstract: Butanol production from corn stover via (acetone-butanol-ethanol) ABE fermentation under vacuum was studied in this work. The reactor operating strategies considered were batch, fed-batch and continuous. The integrated reactor and vacuum separation process includes energy integration by a heat-pump system as well. A mathematical model describing the dynamics of the integrated reactors and the network of compressors and heat exchangers has been developed. The dynamic process models were used to select the optimum production strategy using economic optimisation where a methodology to determine the effect of scheduling of parallel reactor operation on the sizing of the heat-pump system was developed. The results suggest that the optimal operating mode for the integrated reaction system was fed-batch. Although the fed-batch process had the highest economic potential (37.8 MM USD), the compressor work for batch process operation (36.6 MM USD) was the lowest (1.8 MJ/kg ABE, 18% lower than that of fed-batch). Continuous process operation demonstrated the lowest economic potential (23.8 MM USD) and the highest compression work (2.87 MJ/kg ABE). The energy requirements of the purification system, a double-effect distillation process, were found to be between 3.45 and 4.14 MJ/kg ABE.