(N‐Phosphinoamidinate)cobalt‐Catalyzed Hydroboration: Alkene Isomerization Affords Terminal Selectivity. Issue 43 (3rd September 2014)

• Record Type: Journal Article
• Authors: Ruddy, Adam J.; Sydora, Orson L.; Small, Brooke L.; Stradiotto, Mark; Turculet, Laura
• Is Part Of: Chemistry. Volume 20:Issue 43(2014)
• Page Start: 13918
• Page End: 13922
• Publication Date: 2014-09-03
• Subjects: alkene isomerization -- cobalt -- hydroboration -- ketones -- N‐phosphinoamidinate; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201403945
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract: Herein we establish the utility of a three‐coordinate ( N ‐phosphinoamidinate)cobalt(amido) pre‐catalyst that is capable of effecting challenging alkene isomerization/hydroboration processes at room temperature, leading to the selective terminal addition of the boron group. Abstract : Chain‐walking hydroborations : A three‐coordinate ( N ‐phosphinoamidinate)cobalt(amido) pre‐catalyst is capable of effecting challenging alkene isomerization/hydroboration processes at room temperature, leading to the selective terminal addition of the boron group.