A novel route to the synthesis of α-Fe2O3@C@SiO2/TiO2 nanocomposite from the metal-organic framework as a photocatalyst for water treatment. (June 2022)

• Record Type: Journal Article
• Authors: Mousavi, Seyedeh Elaheh; Younesi, Habibollah; Bahramifar, Nader; Tamunaidu, Pramila; Karimi-Maleh, Hassan
• Is Part Of: Chemosphere. Volume 297(2022)
• Publication Date: 2022-06
• Subjects: Metal-organic framework -- Photocatalytic degradation -- Transition state theory; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2022.133992
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: In this study, an attempt was made to synthesize metal-organic frameworks (MOFs) based magnetic iron particles as photocatalysts for textile dye wastewater. Improvement strategy was a novel two-step dry method without using conventional methods to eliminate the consumption of chemical reagents. First, the heterogeneous photocatalyst of Fe-MOFs derived magnetic carbon nanocomposite with carboxylic acid surface functional groups (Fe@C–COOH) was achieved. Next, the α-Fe2 O3 @C@SiO2 /TiO2 was successfully synthesized followed by a sol-gel method to coat the SiO2 shell and a solvothermal method to coat the surface of the intermediate TiO2 particles. The as-synthesized nanocomposite materials were characterized and physicochemical analytical equipment. Further, the investigation on magnetic photocatalytic nanocomposite α-Fe2 O3 @C@SiO2 /TiO2 performance of dye degradation and photocatalytic activity on Reactive yellow 145 (RY145), using as an indicator was conducted. The as-synthesized nanocomposite particles were characterized using X-ray powder diffraction (XRD), thermogravimetric analysis (TGA), Fourier-transform infrared spectroscopy (FT-IR), vibrating sample magnetometer (VSM), X-ray energy dispersive spectroscopy (EDX), and scanning electron microscopy (SEM) techniques. The structural characterization of the as-synthesized materials proved that these methods generate oxygen-containing functional groups, such as, –OH, –CO, and –COOH, which increases the polarity and hydrophilicity of the photocatalyst. The photocatalytic oxidation of RY145 dye under UVc light was discussed by the apparent first-order reaction rate and the kinetic model of the Langmuir-Hinshelwood followed a better fitting. The optimal performance of the composite is at pH = 2, 15 mg/100 mL of photocatalyst dose, 150 mg/L concentration of the dye RY145 at 25 °C temperature under UVc lamp irradiation for 90 min, and with the apparent reaction rate constant was 0.0165 min −1 . The thermodynamic analysis of activation parameters computed by the Eyring model and based on transition state theory (TST), an endothermic reaction with a positive value for Δ ‡ H o (50.16 kJ mol −1 ) and a negative value for Δ ‡ S o (−153 J/mol K) both contribute toward achieving positive values for Δ ‡ G o and a nonspontaneous process. The proposed α-Fe2 O3 @C@SiO2 /TiO2 demonstrated a high capability of photocatalytic degradation up to 97% after five successive cycles at the optimal condition compared to that of Fe3 O4 @C (18.74%) and Fe@C–COOH (77.9%) without reusability. Graphical abstract: Image 1 Highlights: Fabrication and analysis of metal-organic framework based photocatalytic materials. Effective degradation of recalcitrant organic pollutants for wastewater treatment. Thermodynamic properties of activation were evaluated in the photocatalytic process. As-prepared magnetic photocatalyst revealed good separation efficiency and recovery.