Green β-cyclodextrin-based corrosion inhibitors: Recent developments, innovations and future opportunities. (15th September 2022)

• Record Type: Journal Article
• Authors: Berdimurodov, Elyor; Eliboyev, Ilyos; Berdimuradov, Khasan; Kholikov, Abduvali; Akbarov, Khamdam; Dagdag, Omar; Rbaa, Mohamed; El Ibrahimi, Brahim; Verma, Dakeshwar Kumar; Haldhar, Rajesh; Arrousse, Nadia
• Is Part Of: Carbohydrate polymers. Volume 292(2022)
• Publication Date: 2022-09-15
• Subjects: Ultraviolet photoelectron spectroscopy UPS -- β-cyclodextrin β-CD -- Weight loss WL -- β-CD modifications with natural polymer β-CD-XG -- Fourier transform infrared spectroscopy FT-IR -- Differential scanning calorimeter DSC -- Complexation-induced shifts CIS -- Corrosion potential Ecorr -- Transmission Electron Microscopy TEM -- Electron dispersive X-ray spectroscopy EDS or EDX -- Diffusion-ordered spectroscopy DOSY -- National Association of Corrosion Engineers NACE -- Scanning electron microscopy SEM -- Angular dependent X-ray photoelectron spectroscopy ADXPS -- Electrochemical impedance spectroscopy EIS -- Potentiodynamic polarization PDP -- X-ray photoelectron spectroscopy XPS -- Proton nuclear magnetic resonance spectra 1H NMR -- Carbon nuclear magnetic resonance spectra 13C NMR -- Laser scanning confocal microscopy LSCM -- Charge transfer resistance Rct -- X-ray diffraction XRD -- Electrochemical frequency spectroscopy EFM -- Linear polarization resistance LPR -- Corrosion current density Icorr; Corrosion inhibitors -- β-Cyclodextrin -- Green materials -- Supramolecular systems -- Nanoparticle -- Graphene oxide -- Nanocarriers; Polysaccharides -- Periodicals; Polysaccharides -- Periodicals; Polysaccharides -- Périodiques; Electronic journals; 547.78
• DOI: 10.1016/j.carbpol.2022.119719
• Languages: English
• ISSNs: 0144-8617

Abstract

Abstract: β-Cyclodextrin-based compounds are used to develop and innovate materials that protect against corrosion due to their sustainability, low cost, environmental friendliness, excellent water solubility and high inhibition efficiency. However, corrosion potentials of β-CD-based compounds were not reviewed with the modern trends. The essence of the problem is that a deep understanding of the development and innovation of β-CD-based compounds as corrosion inhibitors is very important in creating next-generation materials for corrosion protection. In this review, the fundamental behaviour, importance, developments and innovations of β-CD modified with natural and synthetic polymers, β-CD grafted with the organic compounds, β-CD-based supramolecular (host-guest) systems with organic molecules, polymer β-CD-based supramolecular (host-guest) systems, β-CD-based graphene oxide materials, β-CD-based nanoparticle materials and β-CD-based nanocarriers as corrosion inhibitors for various metals were reviewed and discussed with recent research works as examples. In addition, the corrosion inhibition of β-CD-based compounds for biocorrosion, microbial corrosion and biofouling was reviewed. It was found that (i) these compounds are sustainable, inexpensive, environmentally friendly, and highly water-soluble and have high inhibition efficiency; (ii) the molecular structure of β-CD makes it an excellent molecular container for corrosion inhibitors compounds; (iii) the β-CD is excellent core to develop the next generation of corrosion inhibitors. It is recommended that (i) β-CD compounds would be synthesized by green methods, such as using biological sustainable catalysts and green solvents, green methods include irradiation or heating, energy-efficient microwave irradiation, mechanochemical mixing, solid-state reactions, hydrothermal reactions and multicomponent reactions; (ii) this review will be helpful in creating, enhancing and innovating the next green and efficient materials for future corrosion protection in high-impact industries. Graphical abstract: Unlabelled Image Highlights: β-CD is the excellent skeleton for the synthesis of green and efficient anti-corrosion agents. Anti-corrosion power of organic compounds is dramatically rose with the β-CD rings. The supramolecular system of β-CD based compounds influences the inhibition and adsorption mechanisms. The influence of the molecular structure of β-CD on inhibition characteristics is described. Developments, innovations, current trends and future outlook in β-CD derivatives as corrosion inhibitors are reviewed.