Template Engineering of CuBi2O4 Single‐Crystal Thin Film Photocathodes. Issue 39 (19th July 2020)

• Record Type: Journal Article
• Authors: Lee, Jongmin; Yoon, Hongji; Choi, Kyoung Soon; Kim, Seungkyu; Seo, Sehun; Song, Jaesun; Choi, Byeong‐Uk; Ryu, Jiseung; Ryu, Sangwoo; Oh, Jihun; Jeon, Cheolho; Lee, Sanghan
• Is Part Of: Small. Volume 16:Issue 39(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-07-19
• Subjects: CuBi 2O 4 -- single‐crystal thin films -- template engineering; Nanotechnology -- Periodicals; Nanoparticles -- Periodicals; Microtechnology -- Periodicals; 620.5
• DOI: 10.1002/smll.202002429
• Languages: English
• ISSNs: 1613-6810

Abstract

Abstract: To develop strategies for efficient photo‐electrochemical water‐splitting, it is important to understand the fundamental properties of oxide photoelectrodes by synthesizing and investigating their single‐crystal thin films. However, it is challenging to synthesize high‐quality single‐crystal thin films from copper‐based oxide photoelectrodes due to the occurrence of significant defects such as copper or oxygen vacancies and grains. Here, the CuBi2 O4 (CBO) single‐crystal thin film photocathode is achieved using a NiO template layer grown on single‐crystal SrTiO3 (STO) (001) substrate via pulsed laser deposition. The NiO template layer plays a role as a buffer layer of large lattice mismatch between CBO and STO (001) substrate through domain‐matching epitaxy, and forms a type‐II band alignment with CBO, which prohibits the transfer of photogenerated electrons toward bottom electrode. The photocurrent densities of the CBO single‐crystal thin film photocathode demonstrate −0.4 and −0.7 mA cm −2 at even 0 VRHE with no severe dark current under illumination in a 0.1 m potassium phosphate buffer solution without and with H2 O2 as an electron scavenger, respectively. The successful synthesis of high‐quality CBO single‐crystal thin film would be a cornerstone for the in‐depth understanding of the fundamental properties of CBO toward efficient photo‐electrochemical water‐splitting. Abstract : It is important to understand the fundamental photo‐electrochemical properties of CuBi2 O4 single‐crystal thin film photocathodes toward efficient photo‐electrochemical water‐splitting. The synthesis of high‐quality CuBi2 O4 thin films is successfully achieved through domain matching epitaxy relationship between CuBi2 O4 and NiO. The stable photocurrent densities of CuBi2 O4 single‐crystal thin film photocathode occur at a potential of even 0 VRHE without severe dark‐current.