Thionylimido Complexes. Issue 22 (12th August 2020)

• Record Type: Journal Article
• Authors: McGeachie, Liam J. R.; Carpenter‐Warren, Cameron L.; Cordes, David B.; Bühl, Michael; Gray, Steven J.; Hua, Guoxiong; Slawin, Alexandra M. Z.; Woollins, J. Derek
• Is Part Of: Zeitschrift für anorganische und allgemeine Chemie. Volume 646:Issue 22(2020)
• Page Start: 1795
• Page End: 1798
• Publication Date: 2020-08-12
• Subjects: Thionylimide -- Thiazate -- Antimony complex -- Antimony -- X‐ray diffraction; Chemistry, Inorganic -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1002/zaac.202000238
• Languages: English
• ISSNs: 0044-2313

Abstract

Abstract : An improved route to d‐block and main group NSO complexes is presented including the synthesis of the first antimony(V) complexes, (Ar3 Sb(NSO)2 ), and copper examples [CuBipy(PPh3 )NSO]. The structures of eight complexes are reported. The observed variation in M–N–S bond angles is due to the combination of orbital overlap (ligand‐to‐metal bonding) and the degree of ionicity of the bonding. Abstract :