High-entropy FeCoNiMn (oxy)hydroxide as high-performance electrocatalyst for OER and boosting clean carrier production under quasi-industrial condition. (1st July 2022)

• Record Type: Journal Article
• Authors: He, Lixiang; Wang, Ni; Sun, Baolong; Zhong, Li; Yao, Mengqi; Hu, Wencheng; Komarneni, Sridhar
• Is Part Of: Journal of cleaner production. Volume 356(2022)
• Publication Date: 2022-07-01
• Subjects: Oxygen evolution reaction -- Electrocatalysts -- High current density -- Quasi-industrial condition -- Stability -- Large area; Factory and trade waste -- Management -- Periodicals; Manufactures -- Environmental aspects -- Periodicals; Déchets industriels -- Gestion -- Périodiques; Usines -- Aspect de l'environnement -- Périodiques; 628.5
• DOI: 10.1016/j.jclepro.2022.131680
• Languages: English
• ISSNs: 0959-6526

Abstract

Abstract: Hydrogen is recognized as the most promising sustainable energy carrier. It is important to boost oxygen evolution reaction (OER) to produce more hydrogen. High-entropy compounds are a potential category of electrocatalysts for water splitting due to their outstanding reactivity and stability. Noble metal-free high-entropy FeCoNiMn (oxy)hydroxide was synthesized over a large area of 100 cm 2 on nickel foam using a facile approach of one-step electrodeposition. High-entropy FeCoNiMnOOH led to outstanding OER activity with a low overpotential of 282 mV at current density of 100 mA cm −2 and showed excellent performance at room temperature as determined by the stability test for over 200 h at a high current density of 500 mA cm −2 in 1.0 M KOH. Under quasi-industrial condition of using 6.0 M KOH solution at 333 K, only 1.64 V was required to reach a high current density of 3000 mA cm −2 . In addition, the high-entropy catalyst maintained its stability at a high current density of 1000 mA cm −2 for over 40 h, suggesting its suitability for practical application. Graphical abstract: High-entropy (oxy)hydroxide with excellent OER performance has boosted hydrogen production. Image 1 Highlights: Large size electrocatalyst is synthesized by facile electrodeposition method. High-entropy material displays low overpotential of 291 mV at 100 mA cm −2 for OER. High-entropy material for quasi-industrial water splitting is reported. Only 1.64 V is demanded to reach 3 A cm −2 under the quasi-industrial condition. The stability was over 40 h at 1A cm −2 under quasi-industrial condition.