A ferric guest inside a spin crossover ferrous helicate. Issue 35 (12th April 2022)
- Record Type:
- Journal Article
- Title:
- A ferric guest inside a spin crossover ferrous helicate. Issue 35 (12th April 2022)
- Main Title:
- A ferric guest inside a spin crossover ferrous helicate
- Authors:
- Barrios, Leoní A.
Diego, Rosa
Darawsheh, Mohanad
Martínez, Jesús I.
Roubeau, Oliver
Aromí, Guillem - Abstract:
- Abstract : Encapsulation of an Fe(iii ) tris-oxalate coordination complex inside an Fe(ii ) metallosupramolecular helicate drastically reduces the quantum coherence of the ferric S = 5/2 spin of this ion. Abstract : A designed dimetallic Fe(ii ) helicate made with biphenylene-bridged bispyrazolylpyridine ligands and exhibiting a process of spin crossover at temperatures above ambient is shown to encapsulate an S = 5/2 tris-oxalato Fe(iii ) ion. The spin relaxation dynamics of this guest are strongly reduced upon encapsulation.
- Is Part Of:
- Chemical communications. Volume 58:Issue 35(2022)
- Journal:
- Chemical communications
- Issue:
- Volume 58:Issue 35(2022)
- Issue Display:
- Volume 58, Issue 35 (2022)
- Year:
- 2022
- Volume:
- 58
- Issue:
- 35
- Issue Sort Value:
- 2022-0058-0035-0000
- Page Start:
- 5375
- Page End:
- 5378
- Publication Date:
- 2022-04-12
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d2cc00928e ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 21561.xml