Adsorptive removal of Acid Blue 113 using hydroxyapatite nanoadsorbents synthesized using Peltophorum pterocarpum pod extract. (July 2022)

• Record Type: Journal Article
• Authors: Sodhani, Hriday; Hedaoo, Shantanu; Murugesan, Gokulakrishnan; Pai, Shraddha; Vinayagam, Ramesh; Varadavenkatesan, Thivaharan; Bharath, G.; Haija, Mohammad Abu; Nadda, Ashok Kumar; Govarthanan, Muthusamy; Selvaraj, Raja
• Is Part Of: Chemosphere. Volume 299(2022)
• Publication Date: 2022-07
• Subjects: Hydroxyapatite -- Nanoadsorbents -- Green synthesis -- Peltophorum pterocarpum -- Acid blue 113; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2022.134752
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: The present work reports the study on the green synthesis of hydroxyapatite (HAP) nanoadsorbents using Peltophorum pterocarpum pod extract. HAP nanoadsorbents were characterized by using FESEM, EDS, TEM, XRD, FTIR, XPS, and BET analyses. The results highlighted the high purity, needle-like aggregations, and crystalline nature of the prepared HAP nanoadsorbents. The surface area was determined as 40.04 m 2 /g possessing mesopores that can be related to the high adsorption efficiency of the HAP for the removal of a toxic dye, – Acid Blue 113 (AB 113) from water. Central Composite Design (CCD) was used for optimizing the adsorption process, which yielded 94.59% removal efficiency at the optimum conditions (dose: 0.5 g/L, AB 113 dye concentration: 25 ppm, agitation speed: 173 rpm, and adsorption time: 120 min). The adsorption kinetics followed the pseudo-second-order model (R 2 :0.9996) and the equilibrium data fitted well with the Freundlich isotherm (R 2 :0.9924). The thermodynamic parameters indicated that the adsorption of AB 113 was a spontaneous and exothermic process. The highest adsorption capacity was determined as 153.85 mg/g, which suggested the promising role of green HAP nanoadsorbents in environmental remediation applications. Graphical abstract: Image 1 Highlights: Hydroxyapatite was synthesized using Peltophorum pterocarpum leaf extract. Needle-like aggregates were witnessed in FE-SEM image. A high specific-surface area of 40.04 m 2 /g was observed by BET analysis. Hydroxyapatite was used to adsorb AB 113 dye. Maximum AB 113 dye adsorption capacity was 153.85 mg/g.