Efficient Cr(VI) and phosphate removal from contaminated water using MnTiFeO nanoflakes: Statistical modeling and interpretation. (August 2022)

• Record Type: Journal Article
• Authors: Kondalkar, Milind; Jethave, Ganesh; Fegade, Umesh; Altalhi, Tariq; Inamuddin, ; Farhan Khan, Mohd; Suryawanshi, Kiran E.; Isai, Kalpesh A.; Sonawane, M.S.
• Is Part Of: Journal of physics and chemistry of solids. Volume 167(2022)
• Publication Date: 2022-08
• Subjects: MnTiFeO nanoflakes -- Double-layer model -- Binary system -- Cr(VI) -- And phosphate adsorption; Solids -- Periodicals; Solides -- Périodiques; Solids; Periodicals; 530.41
• DOI: 10.1016/j.jpcs.2022.110715
• Languages: English
• ISSNs: 0022-3697

Abstract

Abstract: MnTiFeO nanoflakes (NF) have been prepared and used to remove Cr(VI) and phosphate from an aqueous solution. The optimum potentials for adsorption of Cr(VI) and phosphate occur at acidic pH and are primarily due to ionic interactions. Langmuir monolayer adsorption is observed. The active sites of NF show some selectivity for Cr(VI) due to various putative interaction modes. The adsorption of Cr(VI) and phosphate are dominated by a multi-docking process, as implied by steric parameters in applied advanced statistical models. The observed selectivity of NF is primarily due to a higher receptor site density for Cr(VI) ions than for phosphate anions. Statistical modeling yields the best fitting of the experimental data for a double-layer in the binary system. MnTiFeO NF can be regarded an effective, competitive, and low-cost adsorbent for the removal of hexavalent Cr and phosphate. The maximum adsorption capacities of MnTiFeO NF for Cr(VI) and phosphate adsorption were evaluated as 166.66 and 163.93 mg/g, respectively. Graphical abstract: Image 1 Highlights: Fe-doped KNbO3 (KN) single crystal has been prepared by a flux method. XRD analysis has confirmed the single-crystal nature of the sample. Differential thermal analysis showed two endothermic peaks attributable to phase transitions. The Curie temperature of Fe-doped KN has been measured as 435 °C, essentially the same as that of undoped KN. The ferroelectric nature of Fe-doped KN is weak.