Is there chiral correlation between graphitic layers in double-wall carbon nanotubes?. (April 2019)

• Record Type: Journal Article
• Authors: He, Maoshuai; Xu, Ziwei; Shang, Danhong; Zhang, Xiuyun; Zhang, Hao; Li, Dong; Jiang, Hua; Kauppinen, Esko; Ding, Feng
• Is Part Of: Carbon. Volume 144(2019)
• Page Start: 147
• Page End: 151
• Publication Date: 2019-04
• Subjects: Double-wall carbon nanotube -- Structure correlation -- Electron diffraction -- Chiral angle difference; Carbon -- Periodicals; Carbone -- Périodiques; Koolstof; Toepassingen; Electronic journals; 546.681
• DOI: 10.1016/j.carbon.2018.12.003
• Languages: English
• ISSNs: 0008-6223

Abstract

Abstract: Because of the unique concentric structure, double-wall carbon nanotubes (DWNTs) possess fascinating properties which depend on the respective chirality of both the outer and the inner tubes. In this work, we study the chiral correlations of DWNTs synthesized by chemical vapor deposition on Fe nanoparticles. Contrary to some recent report, the distribution of chiral angle difference between inner and outer tubes in our work agrees with that calculated for all possible configurations. Remarkably, DWNTs with commensurate structures, i.e . outer and inner tubes have same chiral angles, are observed. The mechanism for the formation of DWNTs with approximately commensurate structures is discussed on the basis of layer by layer model. Furthermore, the interactional energies between the inner and outer walls are calculated to address the stability of different DWNT configurations. This work helps understand the growth mechanism of DWNTs and comprehend their structure stabilities with different configurations. Graphical abstract: Double-wall carbon nanotubes (DWNTs) synthesized by chemical vapor deposition show randomly distributed chiral angle differences between inner and outer tubes. The mechanism for the formation of DWNTs with approximately commensurate structures is discussed based on layer by layer model. The interactional energies between the inner and outer walls are calculated to address the stability of different DWNT configurations. Image 107177