Bio-based porphyrins pyropheophorbide a and its Zn-complex as visible-light photosensitizers for free-radical photopolymerization. Issue 12 (9th March 2022) - Breloy, Louise
Abstract : Two chlorophyll a derivatives, namely pyropheophorbide a and its corresponding zinc(ii ) complex, are used as visible-light photosensitizers for free-radical photopolymerization. Abstract : A chlorophyll a derivative, namely pyropheophorbide a (Pyro ), and the corresponding zinc(ii ) complex (Zn-Pyro ) were used for the first time as visible-light photosensitizers (PS) for free-radical photopolymerization (FRP) when combined with an iodonium salt derivative (Iod) and different amines. The reaction mechanisms involving Pyro and Zn-Pyro coupled with Iod and/or MDEA were deeply investigated using steady-state photolysis, fluorescence experiments, laser-flash photolysis (LFP), and electron-paramagnetic resonance spin trapping (EPR-ST) methods. According to the remarkable absorption properties of Pyro and Zn-Pyro, FRP could occur under blue-light (LED@405 nm and LED@455 nm), and under red-light (LED@625 nm and LED@660 nm) irradiation. Conversions of up to 80% of PEG-diacrylate were obtained using two-component (PS/Iod and PS/amine) or three-component (PS/Iod/amine) photoinitiating systems. Several amines used as co-initiators were compared, and N -methyl-diethanolamine (MDEA) and the bio-based thiol-amine cysteamine (Cys) exhibited very interesting kinetic results. Notably, the performances in FRP obtained with the Zn-Pyro /Iod/Cys system constitute a promising step in the development of a fully bio-based photoinitiating system.